Production process of silver halide emulsion

Abstract

A process for producing a photosensitive silver halide emulsion is disclosed, comprising silver halide grains and a dispersion medium, said process comprising steps of adding a water-soluble silver solution, an aqueous alkali halide solution and an aqueous solution of gelatin having a molecular weight of 5,000 to 30,000 or less to a mixing vessel different from a reactor for the production of emulsion to prepare silver halide fine grains, adding the silver halide fine grains to the reactor for the production of emulsion to grow silver halide grains, and ultrafiltering the silver halide grains during the addition of silver halide fine grains, wherein 50% or more of the entire projected area of said emulsion grains is occupied by silver halide tabular grains having an aspect ratio of 10 or more and a thickness of 0.15 μm or less.

What is claimed is:  
     
         1 . A process for producing a photosensitive silver halide emulsion comprising silver halide grains and a dispersion medium, said process comprising steps of adding a water-soluble silver solution, an aqueous alkali halide solution and an aqueous solution of gelatin having a molecular weight of 5,000 to 30,000 or less to a mixing vessel different from a reactor for the production of emulsion to prepare silver halide fine grains, adding the silver halide fine grains to the reactor for the production of emulsion to grow silver halide grains, and ultrafiltering the silver halide grains during the addition of silver halide fine grains, wherein 50% or more of the entire projected area of said emulsion grains is occupied by silver halide tabular grains having an aspect ratio of 10 or more and a thickness of 0.15 μm or less.  
     
     
         2 . The process for producing a silver halide emulsion as claimed in  claim 1 , wherein the silver halide grains present in the reactor for the production of emulsion are ultrafiltered under variable temperature conditions before the addition of said silver halide fine grains.  
     
     
         3 . The process for producing a silver halide emulsion as claimed in  claim 1 , wherein the residence time of said water-soluble silver salt, aqueous alkali halide solution and aqueous gelatin solution in a mixing space of said mixing vessel is from 0.001 to 10 seconds.  
     
     
         4 . The process for producing a silver halide emulsion as claimed in  claim 1 , wherein said mixing vessel comprises a stirring tank and at least two stirring blades in the stirring tank, an aqueous solution of water-soluble silver salt and an aqueous solution of water-soluble halide are supplied through supply ports provided in the stirring tank of the mixing vessel, the stirring state in mixing the aqueous solutions supplied is controlled by the stirring blades having no rotary shaft protruding through a wall of the stirring tank and disposed to space at the positions facing each other in the stirring tank, and the silver halide fine grains produced after the completion of stirring treatment are discharged from the discharge port provided in the stirring tank.  
     
     
         5 . The process for producing a silver halide emulsion as claimed in  claim 1 , wherein the average equivalent-circle diameter of said silver halide fine grains is 40% or more of the number average thickness of said silver halide tabular grains under growing.  
     
     
         6 . The process for producing a silver halide emulsion as claimed in  claim 1 , wherein the coefficient of variation in the equivalent-circle diameter of said silver halide fine grains is 30% or less.  
     
     
         7 . The process for producing a silver halide emulsion as claimed in  claim 1 , wherein 50% or more of the entire projected area is occupied by grains having an equivalent-circle diameter of 3.0 μm or more.  
     
     
         8 . The process for producing a silver halide emulsion as claimed in  claim 1 , wherein 70% or more of the entire projected area is occupied by hexagonal tabular grains having an epitaxial projection part at least at one apex.  
     
     
         9 . The process for producing a silver halide emulsion as claimed in  claim 1 , wherein said emulsion is produced through nucleation, ripening and growth steps and the total silver concentration in the silver halide emulsion at the start of ripening step is from 0.0015 to 0.15 mass %.  
     
     
         10 . The process for producing a silver halide emulsion as claimed in  claim 1 , wherein the reactor temperature in the nucleation step of adding an aqueous silver solution and an aqueous halide solution is 5° C. or less.  
     
     
         11 . A process for producing a silver halide emulsion through nucleation, ripening and growth steps, said silver halide emulsion being a photosensitive silver halide emulsion comprising silver halide grains and a dispersion medium, wherein 50% or more of the entire projected area of grains is occupied by silver halide tabular grains having an aspect retio of 10 or more, the total silver concentration in the silver halide emulsion at the start of ripening step is from 0.0015 to 0.15 mass %, and ultrafiltration is used in a part of the emulsion preparation steps.  
     
     
         12 . The process for producing a silver halide emulsion through nucleation, ripening and growth steps as claimed in  claim 11 , wherein the reactor temperature in the nucleation step of adding an aqueous silver solution and an aqueous halide solution is from 0 to 5° C.  
     
     
         13 . The process for producing a silver halide emulsion through nucleation, ripening and growth steps as claimed in  claim 11 , wherein the silver halide tabular grains have an equivalent-circle diameter of 3.0 μm or more and a thickness of 0.15 μm or less.