US2004054117A1PendingUtilityA1

New polyurethanes and their use for the thickening of aqueous systems

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Priority: Mar 12, 2001Filed: Aug 18, 2003Published: Mar 18, 2004
Est. expiryMar 12, 2021(expired)· nominal 20-yr term from priority
Inventors:Christian WamprechtJan MazanekPeter ManshausenFrank Sauer
C09D 7/43C08G 18/286C08G 18/3275C08G 18/2825C08G 18/482C08G 18/3228C08G 18/5045C09D 175/08C08L 75/04C08G 18/71C08G 18/2865C08G 18/755C08G 18/4837C08G 18/3234
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Claims

Abstract

The invention relates to a water-soluble or water-dispersible polyurethane which is the reaction product of A) at least one polyether polyol a1) having an average functionality of ≧3 and at least one urethane group-containing polyether polyol a2) having an average functionality of ≧4, B) at least one monoalcohol with 6 to 22 carbon atoms, C) at least one (cyclo)aliphatic and/or aromatic diisocyanate D) at least one oxime, monoamine and/or diamine with 2 to 18 carbon atoms, E) optionally at least one monoisocyanate with 4 to 18 carbon atoms, and F) optionally at least one polyisocyanate having an average functionality of >2 wherein the starting NCO/OH equivalent ratio is between 0.5:1 to 1.2:1 having a particularly efficient thickening effect in the high-shear range, as well as their use for the thickening of aqueous systems.

Claims

exact text as granted — not AI-modified
What is claimed is:  
     
         1 . A water-soluble or water-dispersible polyurethane comprising a reaction product of 
 A) at least one polyether polyol a1) having an average functionality of ≧3 and at least one urethane group-containing polyether polyol a2) having an average functionality of ≧4,    B) at least one monoalcohol with 6 to 22 carbon atoms,    C) at least one (cyclo)aliphatic and/or aromatic diisocyanate    D) at least one oxime, monoamine and/or diamine with 2 to 18 carbon atoms,    E) optionally at least one monoisocyanate with 4 to 18 carbon atoms, and    F) optionally at least one polyisocyanate having an average functionality of >2    wherein the starting NCO/OH equivalent ratio is between 0.5:1 to 1.2:1.    
     
     
         2 . The polyurethane of  claim 1  wherein the polyether polyol a1) has an average functionality of 3 to 4.  
     
     
         3 . The polyurethane of  claim 1  wherein the polyether polyol a1) has an average functionality of 4 to 6.  
     
     
         4 . The polyurethane of  claim 1  wherein the monoalcohol B) has 6 to 18 carbon atoms.  
     
     
         5 . The polyurethane of  claim 1  wherein the monoalcohol B) has 8 to 18 carbon atoms.  
     
     
         6 . The polyurethane of  claim 1  wherein the monoalcohol B) has 8 to 14 carbon atoms.  
     
     
         7 . The polyurethane of  claim 1  wherein the diisocyanate C) is a (cyclo)aliphatic diisocyanate.  
     
     
         8 . The polyurethane of  claim 1  wherein the component D) is an oxime.  
     
     
         9 . The polyurethane of  claim 1  wherein the component D) is a monoamine.  
     
     
         10 . The polyurethane of  claim 1  wherein the component D) is a diamine and/or polyamine.  
     
     
         11 . The polyurethane of  claim 1  wherein the component D) is an hydroxyfunctional amine.  
     
     
         12 . A process for the production of the water-soluble or water-dispersible polyurethane of  claim 1 , comprising reacting 
 A) a mixture of at least one polyether polyol a1) having a mean functionality of ≧3 and at least 1 urethane group-containing polyether polyol a2) having an average functionality of ≧4,    B) at least one monoalcohol with 6 to 22 carbon atoms,    C) at least one (cyclo)aliphatic and/or aromatic diisocyanate,    D) at least one oxime, monoamine and/or diamine with 2 to 18 carbon atoms,    E) optionally at least one monoisocyanate with 4 to 18 carbon atoms, and    F) optionally at least one polyisocyanate having an average functionality of >2    at a starting NCO/OH equivalent ratio of 0.5:1 to 1.2:1.    
     
     
         13 . The process of  claim 12  wherein the urethane group-containing polyether polyol a2) is a reaction product of the polyether polyol a1) with a diisocyanate.  
     
     
         14 . The process of  claim 12  and  13  wherein the urethane group-containing polyether polyol a2) is a reaction produt of the polyether polyol a1) with polyisocyanates having an average functionality of ≧2.  
     
     
         15 . A process for adjusting the flow properties of an aqueous paint system, adhesive and another aqueous formulation comprising adding the polyurethane of  claim 1  to the aqueous paint system, adhesive and another aqueous formulation.  
     
     
         16 . An aqueous paint system, adhesive and another aqueous formulation comprising the polyurethane of  claim 1.

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