Hair wax products containing waxes, non-volatile oils and volatile hydrophobic materials

Abstract

The wax product for treating or setting up a hairstyle or hairdo includes a composition containing at least one wax or wax-like substance, at least one non-volatile liquid hydrophobic oil and at least one volatile or easily volatilized hydrophobic substance that is a liquid or gas at room temperature. Because of the presence of the volatile substance in the composition a soft wax easily worked in the hair is obtained when the composition is applied to the hair. This soft wax hardens on the hair when the volatile ingredients evaporate. When the composition includes a propellant gas a wax with a larger surface area (wax snow) is produced, which is likewise easily worked into the hair and very effectively fixes or sets the hair.

We claim:  
     
         1 . A hair wax product containing a wax-like composition, wherein said wax-like composition comprises: 
 from 5 to 60% by weight of at least one wax or wax-like substance;    from 5 to 35% by weight of at least one non-volatile, liquid, hydrophobic oil having a melting point below 25° C. and a boiling point above 250° C.; and    from 10 to 80% by weight of at least one easily volatilized, hydrophobic substance that is liquid or gaseous at room temperature and that has a boiling point of not more than 250° C.    
     
     
         2 . The hair wax product as defined in  claim 1 , wherein said wax-like composition has a needle penetration number of not less than 10 at 25° C.  
     
     
         3 . The hair wax product as defined in  claim 1 , wherein said at least one easily volatilized, hydrophobic substance is selected from the group consisting of volatile silicone compounds, hydrocarbons having from five to fourteen carbon atoms, volatile liquid paraffins and volatile liquid isoparaffins.  
     
     
         4 . The hair wax product as defined in  claim 1 , wherein said wax-like composition comprises from 3 to 20 percent by weight of an emulsifier.  
     
     
         5 . The hair wax product as defined in  claim 4 , wherein said emulsifier is selected from the group consisting of addition products of 2 to 30 mol ethylene oxide with fatty alcohols having 8 to 22 carbon atoms; addition products of 2 to 30 mol ethylene oxide with fatty acids containing 12 to 22 carbon atoms; addition products of 2 to 30 mol ethylene oxide with alkylphenols containing 8 to 15 carbon atoms in the alkyl groups; addition products of 1 to 5 mol propylene oxide with fatty alcohols having 8 to 22 carbon atoms; addition products of 1 to 5 mol of propylene oxide with fatty acids containing 12 to 22 carbon atoms; addition products of 1 to 5 mol propylene oxide with alkylphenols containing 8 to 15 carbon atoms in the alkyl groups; fatty acid mono- and diesters having 12 to 22 carbon atoms of addition products of 1 to 30 mol ethylene oxide with glycerol; addition products of 5 to 60 mol of ethylene oxide with castor oil; monoesters, diesters and triesters of phosphoric acid and addition products of 2 to 30 mol of ethylene oxide with fatty alcohols having 8 to 22 carbon atoms; or mixtures thereof.  
     
     
         6 . A non-aerosol spray wax article consisting of a container with a mechanical pumping device and with a spray head or foam head and a sprayable or foamable composition contained in the container, said sprayable or foamable composition comprising 
 from 5 to 60% by weight of at least one wax or wax-like substance;    from 5 to 35% by weight of at least one non-volatile, liquid, hydrophobic oil having a melting point below 25° C. and a boiling point above 250° C.; and    from 10 to 80% by weight of at least one easily volatilized, hydrophobic substance that is liquid or gaseous at room temperature and has a boiling point of not more than 250° C.    
     
     
         7 . The non-aerosol spray wax article as defined in  claim 6 , wherein said at least one easily volatilized, hydrophobic substance is selected from the group consisting of volatile silicone compounds, hydrocarbons having from five to fourteen carbon atoms, volatile liquid paraffins and volatile liquid isoparaffins.  
     
     
         8 . The non-aerosol spray wax article as defined in  claim 6 , wherein said composition comprises from 3 to 20 percent by weight of an emulsifier.  
     
     
         9 . The non-aerosol spray wax article as defined in  claim 8 , wherein said emulsifier is selected from the group consisting of addition products of 2 to 30 mol ethylene oxide with fatty alcohols having 8 to 22 carbon atoms; addition products of 2 to 30 mol ethylene oxide with fatty acids containing 12 to 22 carbon atoms; addition products of 2 to 30 mol ethylene oxide with alkylphenols containing 8 to 15 carbon atoms in the alkyl groups; addition products of 1 to 5 mol propylene oxide with fatty alcohols having 8 to 22 carbon atoms; addition products of 1 to 5 mol of propylene oxide with fatty acids containing 12 to 22 carbon atoms; addition products of 1 to 5 mol propylene oxide with alkylphenols containing 8 to 15 carbon atoms in the alkyl groups; fatty acid mono- and diesters having 12 to 22 carbon atoms of addition products of 1 to 30 mol ethylene oxide with glycerol; addition products of 5 to 60 mol of ethylene oxide with castor oil; monoesters, diesters and triesters of phosphoric acid and addition products of 2 to 30 mol of ethylene oxide with fatty alcohols having 8 to 22 carbon atoms; or mixtures thereof.  
     
     
         10 . An aerosol spray wax article consisting of a pressure resistant container with a spray head or a foam head and a sprayable or foamable composition contained in the pressure resistant container, said sprayable or foamable composition comprising 
 from 5 to 60% by weight of at least one wax or wax-like substance;    from 5 to 35% by weight of at least one non-volatile, liquid, hydrophobic oil having a melting point below 25° C. and a boiling point above 250° C.; and    from 35 to 80% by weight of at least one hydrophobic liquified propellant selected from the group consisting of propane, n-butane, isobutane and fluorinated hydrocarbons.    
     
     
         11 . The aerosol spray wax article as defined in  claim 10 , wherein said at least one wax or wax-like substance is selected from materials which have a needle penetration number of less than 40 at 25° C.  
     
     
         12 . The aerosol spray wax article as defined in  claim 10 , wherein said at least one non-volatile, liquid hydrophobic oil is selected from the group consisting of mineral oils, paraffin oils, isoparaffins and hydrocarbons.  
     
     
         13 . The aerosol spray wax article as defined in  claim 10 , wherein said composition comprises from 3 to 20 percent by weight of an emulsifier.  
     
     
         14 . The aerosol spray wax article as defined in  claim 13 , wherein said emulsifier is selected from the group consisting of addition products of 2 to 30 mol ethylene oxide with fatty alcohols having 8 to 22 carbon atoms; addition products of 2 to 30 mol ethylene oxide with fatty acids containing 12 to 22 carbon atoms; addition products of 2 to 30 mol ethylene oxide with alkylphenols containing 8 to 15 carbon atoms in the alkyl groups; addition products of 1 to 5 mol propylene oxide with fatty alcohols having 8 to 22 carbon atoms; addition products of 1 to 5 mol of propylene oxide with fatty acids containing 12 to 22 carbon atoms; addition products of 1 to 5 mol propylene oxide with alkylphenols containing 8 to 15 carbon atoms in the alkyl groups; fatty acid mono- and diesters having 12 to 22 carbon atoms of addition products of 1 to 30 mol ethylene oxide with glycerol; addition products of 5 to 60 mol of ethylene oxide with castor oil; monoesters, diesters and triesters of phosphoric acid and addition products of 2 to 30 mol of ethylene oxide with fatty alcohols having 8 to 22 carbon atoms; or mixtures thereof.  
     
     
         15 . A hair wax composition containing 
 from 20 to 60% by weight of at least one wax or wax-like substance;    from 10 to 35% by weight of at least one non-volatile, liquid, hydrophobic oil having a melting point below 25° C. and a boiling point above 250° C.; and    from 10 to 35% by weight of at least one easily volatilized, hydrophobic substance, which is liquid at room temperature and having a boiling point of not more than 250° C. and is selected from the group consisting of liquid volatile silicones, hydrocarbons with from 5 to 14 carbon atoms, liquid volatile paraffins and liquid volatile isoparaffins; and    wherein said hair wax composition has a needle penetration number of at least 10 at 25° C.    
     
     
         16 . The hair wax composition as defined in  claim 15 , further comprising from 3 to 20 percent by weight of an emulsifier.  
     
     
         17 . The hair wax composition as defined in  claim 16 , wherein said emulsifier is selected from the group consisting of addition products of 2 to 30 mol ethylene oxide with fatty alcohols having 8 to 22 carbon atoms; addition products of 2 to 30 mol ethylene oxide with fatty acids containing 12 to 22 carbon atoms; addition products of 2 to 30 mol ethylene oxide with alkylphenols containing 8 to 15 carbon atoms in the alkyl groups; addition products of 1 to 5 mol propylene oxide with fatty alcohols having 8 to 22 carbon atoms; addition products of 1 to 5 mol of propylene oxide with fatty acids containing 12 to 22 carbon atoms; addition products of 1 to 5 mol propylene oxide with alkylphenols containing 8 to 15 carbon atoms in the alkyl groups; fatty acid mono- and diesters having 12 to 22 carbon atoms of addition products of 1 to 30 mol ethylene oxide with glycerol; addition products of 5 to 60 mol of ethylene oxide with castor oil; monoesters, diesters and triesters of phosphoric acid and addition products of 2 to 30 mol of ethylene oxide with fatty alcohols having 8 to 22 carbon atoms; or mixtures thereof.  
     
     
         18 . A non-aerosol spray wax article consisting of a container with a mechanical pumping device for the container and with a spray head or foam head and a sprayable or foamable composition contained in the container, wherein said sprayable or foamable composition is liquid at room temperature and comprises 
 from 10 to 30% by weight of at least one wax or wax-like substance;    from 10 to 30% by weight of at least one non-volatile, liquid, hydrophobic oil having a melting point below 25° C. and a boiling point above 250° C.; and    from 20 to 70% by weight of at least one easily volatilized, hydrophobic substance which is liquid at room temperature and has a boiling point of from 30 to 100° C.    
     
     
         19 . The non-aerosol spray wax article as defined in  claim 18 , wherein said composition comprises from 3 to 20 percent by weight of an emulsifier.  
     
     
         20 . The non-aerosol spray wax article as-defined in  claim 19 , wherein said emulsifier is selected from the group consisting of addition products of 2 to 30 mol ethylene oxide with fatty alcohols having 8 to 22 carbon atoms; addition products of 2 to 30 mol ethylene oxide with fatty acids containing 12 to 22 carbon atoms; addition products of 2 to 30 mol ethylene oxide with alkylphenols containing 8 to 15 carbon atoms in the alkyl groups; addition products of 1 to 5 mol propylene oxide with fatty alcohols having 8 to 22 carbon atoms; addition products of 1 to 5 mol of propylene oxide with fatty acids containing 12 to 22 carbon atoms; addition products of 1 to 5 mol propylene oxide with alkylphenols containing 8 to 15 carbon atoms in the alkyl groups; fatty acid mono- and diesters having 12 to 22 carbon atoms of addition products of 1 to 30 mol ethylene oxide with glycerol; addition products of 5 to 60 mol of ethylene oxide with castor oil; monoesters, diesters and triesters of phosphoric acid and addition products of 2 to 30 mol of ethylene oxide with fatty alcohols having 8 to 22 carbon atoms; or mixtures thereof.  
     
     
         21 . An aerosol wax spray article consisting of a pressure resistant container with a spray head or a foam head and a sprayable or foamable composition that is liquid at room temperature and contained in the container, said sprayable or foamable composition comprising 
 from 5 to 30% by weight of at least one wax or wax-like substance;    from 5 to 30% by weight of at least one non-volatile, liquid, hydrophobic oil having a melting point below 25° C. and a boiling point above 250° C.; and    from 35 to 80% by weight of at least one hydrophobic liquified propellant selected from the group consisting of propane, n-butane, isobutane and fluorinated hydrocarbons.    
     
     
         22 . The aerosol spray wax article as defined in  claim 21 , wherein said composition comprises from 3 to 20 percent by weight of an emulsifier.  
     
     
         23 . The aerosol spray wax article as defined in  claim 22 , wherein said emulsifier is selected from the group consisting of addition products of 2 to 30 mol ethylene oxide with fatty alcohols having 8 to 22 carbon atoms; addition products of 2 to 30 mol ethylene oxide with fatty acids containing 12 to 22 carbon atoms; addition products of 2 to 30 mol ethylene oxide with alkylphenols containing 8 to 15 carbon atoms in the alkyl groups; addition products of 1 to 5 mol propylene oxide with fatty alcohols having 8 to 22 carbon atoms; addition products of 1 to 5 mol of propylene oxide with fatty acids containing 12 to 22 carbon atoms; addition products of 1 to 5 mol propylene oxide with alkylphenols containing 8 to 15 carbon atoms in the alkyl groups; fatty acid mono- and diesters having 12 to 22 carbon atoms of addition products of 1 to 30 mol ethylene oxide with glycerol; addition products-of 5 to 60 mol of ethylene oxide with castor oil; monoesters, diesters and triesters of phosphoric acid and addition products of 2 to 30 mol of ethylene oxide with fatty alcohols having 8 to 22 carbon atoms; or mixtures thereof.