Developing solvent for photopolymerizable printing plates

Abstract

Flexographic printing plates are produced by exposing the photopolymer plates to a light source and washing out (developing) the masked out, non-exposed areas with a solvent. The invention provides methyl ester solvents suitable for use in the development of photopolymer printing plates. The solvents, which include methyl esters alone or mixed with co-solvents and/or non-solvents, are effective in developing a large number of different photopolymer printing plates and can produce images superior to those obtained with commercially available solvents currently used in such applications.

What is claimed is:  
     
         1 . A method for the development of photopolymerizable flexographic relief printing plates comprising 
 selecting a developing solvent, said developing solvent comprising at least one methyl ester; and    washing an exposed flexographic relief printing plate with said developing solvent to develop and image by dissolving and washing away non-exposed photopolymerizable material.    
     
     
         2 . The method of  claim 1 , wherein the photopolymerizable flexographic relief printing plates is selected from the group consisting of block co-polymers of styrene and butadiene, block co-polymers of styrene and isoprene, co-polymers of butadiene and acrylonitrile, terpolymers of butadiene, acrylonitrile, and acrylic acid.  
     
     
         3 . The method of  claim 1 , wherein the methyl ester is methyl ester of fatty acids with 8-18 carbons.  
     
     
         4 . The method of  claim 1 , wherein the developing solvent further comprising a co-solvent.  
     
     
         5 . The method of  claim 4 , wherein the co-solvent is selected from the group consisting of n-butanol, 2-ethoxyethanol, benzyl alcohol, ethanol, methanol, propanol, isopropanol, alpha terpineol, dipropylene glycol methyl ether, 2-butoxyethanol, isopropyl alcohol, and 2-(2-butoxyethoxy) ethanol, cyclopentanol, cyclohexanol, cycloheptanol, substituted cyclopentanol, substituted cyclohexanol, substituted cycloheptanol, cyclopentyl substituted alcohol, cyclohexyl substituted alcohol, and cycloheptyl substituted alcohol.  
     
     
         6 . The method of  claim 5 , wherein the substituted cyclohexanol is 4-ethycyclohexanol.  
     
     
         7 . The method of  claim 5 , wherein the substituted cyclopentanol is 2,3 dimethylcyclopentanol.  
     
     
         8 . The method of  claim 5 , wherein the cyclohexyl substituted alcohol is cyclohexylpropanol.  
     
     
         9 . The method of  claim 5 , wherein the cyclopentyl substituted alcohol is 4-cyclopentylpentanol.  
     
     
         10 . The method of  claim 1 , wherein the developing solvent further comprising a non-solvent.  
     
     
         11 . The method of  claim 10 , wherein the non-solvent is selected from the group consisting of aliphatic petroleum distillates, naphthas, paraffinic solvents, hydro-treated petroleum distillates, mineral oil, mineral spirits, ligroin, decane, octane, and hexane.  
     
     
         12 . The method of  claim 1 , wherein the developing solvent further comprising a co-solvent and a non-solvent.  
     
     
         13 . The method of  claim 12 , wherein the co-solvent is selected from the group consisting of n-butanol, 2-ethoxyethanol, benzyl alcohol, ethanol, methanol, propanol, isopropanol, alpha terpineol, dipropylene glycol methyl ether, 2-butoxyethanol, isopropyl alcohol, and 2-(2-butoxyethoxy) ethanol, cyclopentanol, cyclohexanol, cycloheptanol, substituted cyclopentanol, substituted cyclohexanol, substituted cycloheptanol, cyclopentyl substituted alcohol, cyclohexyl substituted alcohol, and cycloheptyl substituted alcohol.  
     
     
         14 . The method of  claim 12 , wherein the non-solvent is selected from the group consisting of aliphatic petroleum distillates, naphthas, paraffinic solvents, hydro-treated petroleum distillates, mineral oil, mineral spirits, ligroin, decane, octane, and hexane.  
     
     
         15 . The method of  claim 12 , wherein the methyl ester is present in an amount of about 50-70% by volume, the co-solvent is present in an amount of about 20-50% by volume, and the non-solvent is present in an amount of about 10-30% by volume.  
     
     
         16 . The method of  claim 1 , further comprising drying the flexographic relief printing plate to remove the developing solvent.  
     
     
         17 . A developing solvent for the development of photopolymerizable flexographic relief printing plates comprising at least one methyl ester effective to remove non-exposed photopolymerizable material.  
     
     
         18 . The developing solvent of  claim 17 , wherein the methyl ester is methyl ester of fatty acids with 8-18 carbons.  
     
     
         19 . The developing solvent of  claim 17 , wherein the developing solvent further comprising a co-solvent.  
     
     
         20 . The developing solvent of  claim 19 , wherein the co-solvent is selected from the group consisting of n-butanol, 2-ethoxyethanol, benzyl alcohol, ethanol, methanol, propanol, isopropanol, alpha terpineol, dipropylene glycol methyl ether, 2-butoxyethanol, isopropyl alcohol, and 2-(2-butoxyethoxy) ethanol, cyclopentanol, cyclohexanol, cycloheptanol, substituted cyclopentanol, substituted cyclohexanol, substituted cycloheptanol, cyclopentyl substituted alcohol, cyclohexyl substituted alcohol, and cycloheptyl substituted alcohol.  
     
     
         21 . The developing solvent of  claim 20 , wherein the substituted cyclohexanol is 4-ethycyclohexanol.  
     
     
         22 . The developing solvent of  claim 20 , wherein the substituted cyclopentanol is 2,3 dimethylcyclopentanol.  
     
     
         23 . The developing solvent of  claim 20 , wherein the cyclohexyl substituted alcohol is cyclohexylpropanol.  
     
     
         24 . The developing solvent of  claim 20 , wherein the cyclopentyl substituted alcohol is 4-cyclopentylpentanol.  
     
     
         25 . The developing solvent of  claim 17 , further comprising a non-solvent.  
     
     
         26 . The developing solvent of  claim 25 , wherein the non-solvent is selected from the group consisting of aliphatic petroleum distillates, naphthas, paraffinic solvents, hydro-treated petroleum distillates, mineral oil, mineral spirits, ligroin, decane, octane, and hexane.  
     
     
         27 . The developing solvent of  claim 17 , further comprising a co-solvent and a non-solvent.  
     
     
         28 . The developing solvent of  claim 27 , wherein the co-solvent is selected from the group consisting of n-butanol, 2-ethoxyethanol, benzyl alcohol, ethanol, methanol, propanol, isopropanol, alpha terpineol, dipropylene glycol methyl ether, 2-butoxyethanol, isopropyl alcohol, and 2-(2-butoxyethoxy) ethanol, cyclopentanol, cyclohexanol, cycloheptanol, substituted cyclopentanol, substituted cyclohexanol, substituted cycloheptanol, cyclopentyl substituted alcohol, cyclohexyl substituted alcohol, and cycloheptyl substituted alcohol.  
     
     
         29 . The developing solvent of  claim 27 , wherein the non-solvent is selected from the group consisting of aliphatic petroleum distillates, naphthas, paraffinic solvents, hydro-treated petroleum distillates, mineral oil, mineral spirits, ligroin, decane, octane, and hexane.  
     
     
         30 . The developing solvent of  claim 27 , wherein the methyl ester is present in an amount of about 50-70% by volume, the co-solvent is present in an amount of about 20-50% by volume, and the non-solvent is present in an amount of about 10-30% by volume.