Information recording medium and method for producing the same

Abstract

An information recording medium which ensures high reliability and favorable overwrite cyclability is provided, even when an interface layer is not provided between a recording layer and a dielectric layer. The recording layer 4 and the dielectric layers 2 and 6 are formed on the surface of the substrate 1. In the recording layer 4, a phase change is generated between a crystal phase and an amorphous phase by irradiation of light or application of an electric energy. The dielectric layers 2 and 6 are Zr—Cr—O-based material layers comprising Zr, Cr and O, preferably consisting essentially of material expressed, for example, with the formula (ZrO 2 ) M (Cr 2 O 3 ) 100-M (mol %) wherein 20≦M≦80.

What is claimed is:  
     
         1 . An information recording medium comprising: 
 a substrate;    a recording layer wherein a phase change between a crystal phase and an amorphous phase is generated by irradiation of light or application of an electric energy; and    a Zr—Cr—O-based material layer comprising Zr, Cr, and O wherein the content of Zr is 30 atomic % or less and the content of Cr is in the range of 7 atomic % to 37 atomic %.    
     
     
         2 . The information recording medium according to  claim 1 , wherein the Zr—Cr—O-based material layer consists essentially of a material expressed with the formula (1): 
       Zr Q Cr R O 100-Q-R  (atomic %)  (1) 
       wherein Q and R are respectively within the range of 0<Q≦30, and 7≦R≦37, and satisfy 20≦Q+R≦60.  
     
     
         3 . The information recording medium according to  claim 1 , wherein the Zr—Cr—O-based material layer further contains Si and consists essentially of a material expressed with the formula (2): 
       Zr U Cr V Si T O 100-U-V-T  (atomic %)  (2) 
       wherein U, V, and T are respectively in the range of 0<U≦30, 7≦V≦37, and 0<T≦14, and satisfy 20≦U+V+T≦60.  
     
     
         4 . The information recording medium according to  claim 1 , wherein the Zr—Cr—O-based material layer consists essentially of a material expressed with the formula (11): 
       (ZrO 2 ) M (Cr 2 O 3 ) 100-M  (mol %)  (11) 
       wherein M is in the range of 20≦M≦80.  
     
     
         5 . The information recording medium according to  claim 2 , wherein the Zr—Cr—O-based material containing Si consists essentially of a material expressed with the formula (21): 
       (ZrO 2 ) X (Cr 2 O 3 ) Y (SiO 2 ) 100-X-Y  (mol %)  (21) 
       wherein X and Y are respectively within the range of 20≦X≦70, and 20≦Y≦60, and satisfy 60≦X+Y≦90.  
     
     
         6 . The information recording medium according to  claim 5 , wherein the material expressed with the formula (21) contains ZrO 2  and SiO 2  at a substantially equal ratio and is expressed with the formula (22): 
       (ZrSiO 4 ) Z (Cr 2 O 3 ) 100-Z  (mol %)  (22) 
       wherein Z is within the range of 25≦Z≦67.  
     
     
         7 . An information recording medium comprising: 
 a substrate;    a recording layer wherein a phase change between a crystal phase and an amorphous phase is generated by irradiation of light or application of an electric energy; and    a layer which consists essentially of a Zr—Cr—Zn—O-based material expressed with the formula (3):   (ZrO 2 ) C (Cr 2 O 3 ) E (D) F (SiO 2 ) 100-C-E-F  (mol %)  (3)   wherein D is ZnS, ZnSe or ZnO, C, E and F are respectively in the range of 20≦C≦60, 20≦E≦60, and 10≦F≦40, and satisfy 60≦C+E+F≦90.    
     
     
         8 . The information recording medium according to  claim 7 , wherein the material expressed with the formula (3) contains ZrO 2  and SiO 2  at a substantially equal ratio and is expressed with the formula (31): 
       (ZrSiO 4 ) A (Cr 2 O 3 ) B (D) 100-A-B  (mol %)  (31) 
         
       wherein D is ZnS, ZnSe or ZnO, A and B are respectively in the range of 25≦A≦54, and 25≦B≦63, and satisfy 50≦A+B≦88.  
     
     
         9 . The information recording medium according to  claim 1 , wherein the phase change is generated reversibly in the recording layer.  
     
     
         10 . The information recording medium according to  claim 7 , wherein the phase change is generated reversibly in the recording layer.  
     
     
         11 . The information recording medium according to  claim 9 , wherein the recording layer comprises a material selected from Ge—Sb—Te, Ge—Sn—Sb—Te, Ge—Bi—Te, Ge—Sn—Bi—Te, Ge—Sb—Bi—Te, Ge—Sn—Sb—Bi—Te, Ag—In—Sb—Te and Sb—Te.  
     
     
         12 . The information recording medium according to  claim 10 , wherein the recording layer comprises a material selected from Ge—Sb—Te, Ge—Sn—Sb—Te, Ge—Bi—Te, Ge—Sn—Bi—Te, Ge—Sb—Bi—Te, Ge—Sn—Sb—Bi—Te, Ag—In—Sb—Te and Sb—Te.  
     
     
         13 . The information recording medium according to  claim 1 , wherein the thickness of the recording layer is 15 nm or less.  
     
     
         14 . The information recording medium according to  claim 7 , wherein the thickness of the recording layer is 15 nm or less.  
     
     
         15 . The information recording medium according to  claim 1 , wherein two or more recording layers are provided.  
     
     
         16 . The information recording medium according to  claim 7 , wherein two or more recording layers are provided.  
     
     
         17 . The information recording medium according to  claim 1 , wherein a first dielectric layer, the recording layer, a second dielectric layer, and a reflective layer are formed in this order on one surface of the substrate, and at least one of the first dielectric layer and the second dielectric layer is the Zr—Cr—O-based material layer which contacts the recording layer.  
     
     
         18 . The information recording medium according to  claim 7 , wherein a first dielectric layer, the recording layer, a second dielectric layer, and a reflective layer are formed in this order on one surface of the substrate, and at least one of the first dielectric layer and the second dielectric layer is the layer consisting essentially of the Zr—Cr—Zn—O-based material expressed with the formula (3) which with the recording layer.  
     
     
         19 . The information recording medium according to  claim 1 , wherein a reflective layer, a second dielectric layer, the recording layer and a first dielectric layer are formed in this order on one surface of the substrate, and at least one of the first dielectric layer and the second dielectric layer is the Zr—Cr—O-based material layer which contacts the recording layer.  
     
     
         20 . The information recording medium according to  claim 7 , wherein a reflective layer, a second dielectric layer, the recording layer and a first dielectric layer are formed in this order on one surface of the substrate, and at least one of the first dielectric layer and the second dielectric layer is the layer consisting essentially of the Zr—Cr—Zn-O-based material expressed with the formula (3) which contacts the recording layer.  
     
     
         21 . A method for producing an information recording medium which comprises a substrate, a recording layer, and a Zr—Cr—O-based material layer comprising Zr, Cr, and O wherein the content of Zr is 30 atomic % or less and the content of Cr is in the range of 7 atomic % to 37 atomic %, the method comprising a process of forming the Zr—Cr—O-based material layer by a sputtering method.  
     
     
         22 . The method according to  claim 21 , wherein a sputtering target consisting essentially of a material expressed with the formula (10): 
       Zr J Cr K O 100-J-K  (atomic %)  (10) 
       wherein J and K are respectively within the range of 3≦J≦24, and 11≦K≦36, and satisfy 34≦J+K≦40, is used in the process of forming the Zr—Cr—O-based material layer by the sputtering method.  
     
     
         23 . The method according to  claim 21 , wherein a sputtering target consisting essentially of a material expressed with the formula (20): 
       Zr G Cr H Si L O 100-G-H-L  (atomic %)  (20) 
       wherein G, H, and L are respectively within the range of  4 ≦G≦21, 11≦H≦30, and 2≦L≦12, and satisfy 34≦G+H+L≦40, is used to form a Zr—Cr—O-based material layer containing Si in the process of forming the Zr—Cr—O-based material layer by the sputtering method.  
     
     
         24 . The method according to  claim 21 , wherein a sputtering target consisting essentially of a material expressed with the formula (110): 
       (ZrO 2 ) m (Cr 2 O 3 ) 100-m  (mol %)  (110) 
       wherein m is within the range of 20≦m≦80, is used in the process of forming the Zr—Cr—O-based material layer by the sputtering method.  
     
     
         25 . The method according to  claim 21 , wherein a sputtering target consisting essentially of a material expressed with the formula (210): 
       (ZrO 2 ) x (Cr 2 O 3 ) y (SiO 2 ) 100-x-y  (mol %)  (210) 
       wherein x and y are respectively within the range of 20≦x≦70, and 20≦y≦60, and satisfy 60≦x+y≦90, is used to form a Zr—Cr—O-based material layer containing Si in the process of forming the Zr—Cr—O-based material layer by the sputtering method.  
     
     
         26 . The method according to  claim 25 , wherein the material expressed with the formula (210) contains ZrO 2  and SiO 2  at a substantially equal ratio and is expressed with the formula (220): 
       (ZrSiO 4 ) z (Cr 2 O 3 ) 100-z  (mol %)  (220) 
       wherein z is within the range of 25≦z≦67.  
     
     
         27 . A method for producing an information recording medium which comprises a substrate, a recording layer, and a layer consisting essentially of a Zr—Cr—Zn—O-based material, the method comprising a process of forming the layer consisting essentially of the Zr—Cr—Zn—O-based material by a sputtering method using a sputtering target consisting essentially of a material expressed with the formula (30): 
       (ZrO 2 ) c (Cr 2 O 3 ) e (D) f (SiO 2 ) 100-c-e-f  (mol %)  (30) 
       wherein, D is ZnS, ZnSe, or ZnO, c, e, and f are respectively within the range of 20≦c≦60, 20≦e≦60, and 10≦f≦40, and satisfy 60≦c+e+f≦90.  
     
     
         28 . The method according to  claim 27 , wherein the material expressed with the formula (30) contains ZrO 2  and SiO 2  at a substantially equal ratio and is expressed with the formula (310): 
       (ZrSiO 4 ) a (Cr 2 O 3 ) b (D) 100-a-b  (mol %)  (310) 
       wherein D is ZnS, ZnSe, or ZnO, a and b are respectively within the range of 25≦a≦54 and 25≦b≦63, and satisfy 50≦a+b≦88.