US2003171538A1PendingUtilityA1

Peptides for inducing cytotoxic T lymphocyte responses to hepatitis B virus

Assignee: SCRIPPS RESEARCH INSTPriority: Aug 26, 1991Filed: Feb 5, 2003Published: Sep 11, 2003
Est. expiryAug 26, 2011(expired)· nominal 20-yr term from priority
A61P 31/12C07K 14/005C12N 2730/10134C12N 2730/10122A61K 2039/572A61K 39/12A61K 40/46A61K 40/11A61K 39/00A61K 2039/57A61K 39/29
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Claims

Abstract

Peptides are used to define epitopes that stimulate HLA-restricted cytotoxic T lymphocyte activity against hepatitis B virus antigens. The peptides are derived from regions of HBV polymerase, and are particularly useful in treating or preventing HBV infection, including methods for stimulating the immune response of chronically infected individuals to respond to HBV antigens.

Claims

exact text as granted — not AI-modified
What is claimed is:  
     
         1 . A CTL inducing peptide comprising from eight to thirteen amino acids, wherein at least a majority of the amino acids are homologous to a corresponding portion of HBpol having the sequence:  
       
         
           
                 
                 
                 
                 
               
                     
                     
                 
                     
                   HBpol4-13 
                   [Seq ID No. 12] 
                     
                 
                 
                 
                 
               
                     
                   Ser-Tyr-Gln-His-Phe-Arg-Lys-Leu-Leu-Leu; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol108-116 
                   [Seq ID No. 13] 
                     
                 
                 
                 
                 
               
                     
                   Arg-Leu-Lys-Leu-Ile-Met-Pro-Ala-Arg; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol139-147 
                   [Seq ID No. 14] 
                     
                 
                 
                 
                 
               
                     
                   Val-Val-Asn-His-Tyr-Phe-Gln-Thr-Arg 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol151-160 
                   [Seq ID No. 15] 
                     
                 
                 
                 
                 
               
                     
                   His-Thr-Leu-Trp-Lys-Ala-Gly-Ile-Leu-Tyr 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol152-161 
                   [Seq ID No. 16] 
                     
                 
                 
                 
                 
               
                     
                   Thr-Leu-Trp-Lys-Ala-Gly-Ile-Leu-Tyr-Lys 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol 455-463 
                   [Seq ID No. 2] 
                     
                 
                 
                 
                 
               
                     
                   Gly-Leu-Ser-Arg-Tyr-Val-Ala-Arg-Leu; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol505-514 
                   [Seq ID No. 17] 
                     
                 
                 
                 
                 
               
                     
                   Leu-Tyr-Ser-His-Pro-Ile-Ile-Leu-Gly-Phe; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol551-559 
                   [Seq ID No. 18] 
                     
                 
                 
                 
                 
               
                     
                   Tyr-Met-Asp-Asp-Val-Val-Leu-Gly-Ala; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol575-583 
                   [Seq ID No. 19] 
                     
                 
                 
                 
                 
               
                     
                   Phe-Leu-Leu-Ser-Leu-Gly-Ile-His-Leu; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol655-663 
                   [Seq ID No. 20] 
                     
                 
                 
                 
                 
               
                     
                   Ala-Leu-Met-Pro-Leu-Tyr-Ala-Cys-Ile; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol748-757 
                   [Seq ID No. 21] 
                     
                 
                 
                 
                 
               
                     
                   Gly-Thr-Asp-Asn-Ser-Val-Val-Leu-Ser-Arg; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol758-766 
                   [Seq ID No. 22] 
                     
                 
                 
                 
                 
               
                     
                   Lys-Tyr-Thr-Ser-Phe-Pro-Trp-Leu-Leu); 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol773-782 
                   [Seq ID No. 3] 
                     
                 
                 
                 
                 
               
                     
                   Ile-Leu-Arg-Gly-Thr-Ser-Phe-Val-Tyr-Val or 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol816-824 
                   [Seq ID No. 5] 
                     
                 
                 
                 
                 
               
                     
                   Phe-Leu-Leu-Ser-Leu-Gly-Ile-His-Leu 
                     
                 
                     
                     
                 
             
                
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
           
         
       
     
     
         2 . The CTL inducing peptide of  claim 1 , which comprises from nine to eleven amino acids.  
     
     
         3 . The CTL inducing peptide of  claim 1 , which comprises:  
       
         
           
                 
                 
                 
                 
               
                     
                     
                 
                     
                   HBpol4-13 
                   [Seq ID No. 12] 
                     
                 
                 
                 
                 
               
                     
                   Ser-Tyr-Gln-His-Phe-Arg-Lys-Leu-Leu-Leu 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol108-116 
                   [Seq ID No. 13] 
                     
                 
                 
                 
                 
               
                     
                   Arg-Leu-Lys-Leu-Ile-Met-Pro-Ala-Arg; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol139-147 
                   [Seq ID No. 14] 
                     
                 
                 
                 
                 
               
                     
                   Val-Val-Asn-His-Tyr-Phe-Gln-Thr-Arg 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol151-160 
                   [Seq ID No. 15] 
                     
                 
                 
                 
                 
               
                     
                   His-Thr-Leu-Trp-Lys-Ala-Gly-Ile-Leu-Tyr 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol152-161 
                   [Seq ID No. 16] 
                     
                 
                 
                 
                 
               
                     
                   Thr-Leu-Trp-Lys-Ala-Gly-Ile-Leu-Tyr-Lys 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol455-463 
                   [Seq ID No. 2] 
                     
                 
                 
                 
                 
               
                     
                   Gly-Leu-Ser-Arg-Tyr-Val-Ala-Arg-Leu; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol505-514 
                   [Seq ID No. 17] 
                     
                 
                 
                 
                 
               
                     
                   Leu-Tyr-Ser-His-Pro-Ile-Ile-Leu-Gly-Phe; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol551-559 
                   [Seq ID No. 18] 
                     
                 
                 
                 
                 
               
                     
                   Tyr-Met-Asp-Asp-Val-Val-Leu-Gly-Ala; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol575-583 
                   [Seq ID No. 19] 
                     
                 
                 
                 
                 
               
                     
                   Phe-Leu-Leu-Ser-Leu-Gly-Ile-His-Leu; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol655-663 
                   [Seq ID No. 20] 
                     
                 
                 
                 
                 
               
                     
                   Ala-Leu-Met-Pro-Leu-Tyr-Ala-Cys-Ile; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol748-757 
                   [Seq ID No. 21] 
                     
                 
                 
                 
                 
               
                     
                   Gly-Thr-Asp-Asn-Ser-Val-Val-Leu-Ser-Arg; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol758-766 
                   [Seq ID No. 22] 
                     
                 
                 
                 
                 
               
                     
                   Lys-Tyr-Thr-Ser-Phe-Pro-Trp-Leu-Leu); 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol773-782 
                   [Seq ID No. 3] 
                     
                 
                 
                 
                 
               
                     
                   Ile-Leu-Arg-Gly-Thr-Ser-Phe-Val-Tyr-Val or 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol816-824 
                   [Seq ID No. 5] 
                     
                 
                 
                 
                 
               
                     
                   Phe-Leu-Leu-Ser-Leu-Gly-Ile-His-Leu 
                     
                 
                     
                     
                 
             
                
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
           
         
       
     
     
         4 . The peptide of  claim 1 , suspended in pharmaceutically acceptable carrier which comprises a liposome.  
     
     
         5 . The CTL inducing peptide of  claim 1 , wherein the peptide also contains a T helper epitope.  
     
     
         6 . The peptide of  claim 1 , conjugated to a immunogenic lipid carrier.  
     
     
         7 . A method for stimulating a cytotoxic T lymphocyte response to hepatitis B virus which comprises exposing cytotoxic T lymphocytes of a host to a peptide which contains a CTL epitope and which comprises from eight to thirteen amino acids, wherein at least a majority of the amino acids are homologous to a corresponding portion of HBpol having the sequence:  
       
         
           
                 
                 
                 
                 
               
                     
                     
                 
                     
                   HBpol14-13 
                   [Seq ID No. 12] 
                     
                 
                 
                 
                 
               
                     
                   Ser-Tyr-Gln-His-Phe-Arg-Lys-Leu-Leu-Leu; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol108-116 
                   [Seq ID No. 13] 
                     
                 
                 
                 
                 
               
                     
                   Arg-Leu-Lys-Leu-Ile-Met-Pro-Ala-Arg; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol139-147 
                   [Seq ID No. 14] 
                     
                 
                 
                 
                 
               
                     
                   Val-Val-Asn-His-Tyr-Phe-Gln-Thr-Arg 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol151-160 
                   [Seq ID No. 15] 
                     
                 
                 
                 
                 
               
                     
                   His-Thr-Leu-Trp-Lys-Ala-Gly-Ile-Leu-Tyr 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol152-161 
                   [Seq ID No. 16] 
                     
                 
                 
                 
                 
               
                     
                   Thr-Leu-Trp-Lys-Ala-Gly-Ile-Leu-Tyr-Lys 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol 455-463 
                   [Seq ID No. 23] 
                     
                 
                 
                 
                 
               
                     
                   Gly-Leu-Ser-Arg-Tyr-Val-Ala-Arg-Leu; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol505-514 
                   [Seq ID No. 17] 
                     
                 
                 
                 
                 
               
                     
                   Leu-Tyr-Ser-His-Pro-Ile-Ile-Leu-Gly-Phe; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol551-559 
                   [Seq ID No. 18] 
                     
                 
                 
                 
                 
               
                     
                   Tyr-Met-Asp-Asp-Val-Val-Leu-Gly-Ala; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol575-583 
                   [Seq ID No. 19] 
                     
                 
                 
                 
                 
               
                     
                   Phe-Leu-Leu-Ser-Leu-Gly-Ile-His-Leu; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol655-663 
                   [Seq ID No. 20] 
                     
                 
                 
                 
                 
               
                     
                   Ala-Leu-Met-Pro-Leu-Tyr-Ala-Cys-Ile 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol748-757 
                   [Seq ID No. 21] 
                     
                 
                 
                 
                 
               
                     
                   Gly-Thr-Asp-Asn-Ser-Val-Val-Leu-Ser-Arg 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol758-766 
                   [Seq ID No. 22] 
                     
                 
                 
                 
                 
               
                     
                   Lys-Tyr-Thr-Ser-Phe-Pro-Trp-Leu-Leu) 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol773-782 
                   [Seq ID No. 3] 
                     
                 
                 
                 
                 
               
                     
                   Ile-Leu-Arg-Gly-Thr-Ser-Phe-Val-Tyr-Val or 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol816-824 
                   [Seq ID No. 5] 
                     
                 
                 
                 
                 
               
                     
                   Phe-Leu-Leu-Ser-Leu-Gly-Ile-His-Leu 
                     
                 
                     
                     
                 
             
                
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
           
         
       
     
     
         8 . The method of  claim 7 , wherein the CTL inducing peptide is:  
       
         
           
                 
                 
                 
                 
               
                     
                     
                 
                     
                   HBpol4-13 
                   [Seq ID No. 12] 
                     
                 
                 
                 
                 
               
                     
                   Ser-Tyr-Gln-His-Phe-Arg-Lys-Leu-Leu-Leu; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol108-116 
                   [Seq ID No. 13] 
                     
                 
                 
                 
                 
               
                     
                   Arg-Leu-Lys-Leu-Ile-Met-Pro-Ala-Arg; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol139-147 
                   [Seq ID No. 14] 
                     
                 
                 
                 
                 
               
                     
                   Val-Val-Asn-His-Tyr-Phe-Gln-Thr-Arg 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol151-160 
                   [Seq ID No. 15] 
                     
                 
                 
                 
                 
               
                     
                   His-Thr-Leu-Trp-Lys-Ala-Gly-Ile-Leu-Tyr 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol152-161 
                   [Seq ID No. 16] 
                     
                 
                 
                 
                 
               
                     
                   Thr-Leu-Trp-Lys-Ala-Gly-Ile-Leu-Tyr-Lys 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol 455-463 
                   [Seq ID No. 2] 
                     
                 
                 
                 
                 
               
                     
                   Gly-Leu-Ser-Arg-Tyr-Val-Ala-Arg-Leu; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol505-514 
                   [Seq ID No. 17] 
                     
                 
                 
                 
                 
               
                     
                   Leu-Tyr-Ser-His-Pro-Ile-Ile-Leu-Gly-Phe; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol551-559 
                   [Seq ID No. 18] 
                     
                 
                 
                 
                 
               
                     
                   Tyr-Met-Asp-Asp-Val-Val-Leu-Gly-Ala; 
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol575-583 
                   [Seq ID No. 19] 
                     
                 
                 
                 
                 
               
                     
                   Phe-Leu-Leu-Ser-Leu-Gly-Ile-His-Leu; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol655-663 
                   [Seq ID No. 20] 
                     
                 
                 
                 
                 
               
                     
                   Ala-Leu-Met-Pro-Leu-Tyr-Ala-Cys-Ile; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol748-757 
                   [Seq ID No. 21] 
                     
                 
                 
                 
                 
               
                     
                   Gly-Thr-Asp-Asn-Ser-Val-Val-Leu-Ser-Arg; 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol758-766 
                   [Seq ID No. 22] 
                     
                 
                 
                 
                 
               
                     
                   Lys-Tyr-Thr-Ser-Phe-Pro-Trp-Leu-Leu); 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol773-782 
                   [Seq ID No. 3] 
                     
                 
                 
                 
                 
               
                     
                   Ile-Leu-Arg-Gly-Thr-Ser-Phe-Val-Tyr-Val or 
                     
                 
                     
                     
                 
                 
                 
                 
                 
               
                     
                   HBpol816-824 
                   [Seq ID No. 5] 
                     
                 
                 
                 
                 
               
                     
                   Phe-Leu-Leu-Ser-Leu-Gly-Ile-His-Leu. 
                     
                 
                     
                     
                 
             
                
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
             
                
               
            
             
                
                
               
            
           
         
       
     
     
         9 . The method of  claim 8 , wherein the host cells exposed to the CTL-inducing peptides are HLA-A2.  
     
     
         10 . The method of  claim 8 , wherein the cytotoxic T cells are removed from the host prior to being exposed to the CTL-inducing peptide.  
     
     
         11 . The method according to  claim 10 , further comprising the step of returning the stimulated CTLs to the host.  
     
     
         12 . The method of  claim 8 , wherein the host has chronic hepatitis B infection or is a hepatitis B carrier.  
     
     
         13 . The method of  claim 8 , wherein the host has acute hepatitis B infection.  
     
     
         14 . The method of  claim 8 , wherein the CTL inducing peptide is administered prophylactically to the host's cells.  
     
     
         15 . The method of  claim 8 , wherein the CTL inducing peptide is administered to the host with a second peptide which elicits a T helper response to HBV.  
     
     
         16 . The method of  claim 15 , wherein the CTL inducing peptide and the T helper inducing peptide are linked.

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