Treatment method of nuclear reactor internal component

Abstract

Surfaces of the structural components of a nuclear power plant exposed to reactor water are wetted with an electroless plating solution containing an electrical insulating substance. The electrical insulating substance has a high resistivity about 10 5 (100000) times those of the structural components of the nuclear power plant or above. A metal film containing the electrical insulating substance is formed on the surfaces of the structural components exposed to the reactor water by wetting the surfaces of the structural components with the electroless plating solution. Thus, the electrochemical corrosion potential of the structural components is reduced regardless of whether hydrogen is injected into the reactor water.

What is claimed is:  
     
         1 . A method of surface-treating structural components of a nuclear power plant, said method comprising wetting the surfaces of the structural components of the nuclear power plant to be exposed to reactor water with an electroless plating solution containing at least either an electrical insulating substance or an oxide having a lattice oxygen anion diffusing property.  
     
     
         2 . The method of surface-treating structural components of a nuclear power plant according to  claim 1 , wherein the structural components are wetted with the electroless plating solution after being processed by a chemical decontamination process using a chemical decontamination liquid.  
     
     
         3 . The method of surface-treating structural components of a nuclear power plant according to  claim 2 , wherein the electroless plating solution is prepared by injecting component substances of the electroless plating solution into the reactor water cleaned by decomposing the chemical decomposition liquid.  
     
     
         4 . The method of surface-treating structural components of a nuclear power plant according to  claim 1 , wherein the electrical insulating substance or the oxide is particles selected from zirconia, alumina, titania, silica, ceria or thoria.  
     
     
         5 . The method of surface-treating structural components of a nuclear power plant according to  claim 4 , wherein the particles of the electrical insulating substance or the oxide has a mean particle diameter in the range of 0.1 to 3 μm.  
     
     
         6 . The method of surface-treating structural components of a nuclear power plant according to  claim 1 , wherein the structural components of the nuclear power plant are a reactor vessel and reactor internal components disposed in the reactor vessel, and the electroless plating solution is injected into the reactor vessel.  
     
     
         7 . The method of surface-treating structural components of a nuclear power plant according to  claim 6 , wherein the electroless plating solution is injected into the reactor vessel through at least one of a recirculation system, a reactor cleaning system and a residual heat removing system.  
     
     
         8 . The method of surface-treating structural components of a nuclear power plant according to  claim 1 , wherein after forming a metal film on the surfaces of the structural components of the nuclear power plant by wetting the surfaces of the structural components with the electroless plating solution, exposing the metal film to water of 100° C. or above.  
     
     
         9 . The method of surface-treating structural components of a nuclear power plant according to  claim 1 , wherein the structural components of the nuclear power plant are installed in the nuclear power plant or removed from the nuclear power plant.  
     
     
         10 . A method of surface-treating structural components of a nuclear power plant, said method comprising wetting the surfaces of the structural components of the nuclear power plant to be exposed to reactor water with an electroless plating solution containing at least either an electrical insulating substance or an oxide having a lattice oxygen anion diffusing property after processing the structural components by a chemical decontamination process.  
     
     
         11 . The method of surface-treating structural components of a nuclear power plant according to  claim 10 , wherein the electrical insulating substance or the oxide is particles selected from zirconia, alumina, titania, silica, ceria or thoria.  
     
     
         12 . The method of surface-treating structural components of a nuclear power plant according to  claim 11 , wherein the particles of the electrical insulating substance or the oxide has a mean particle diameter in the range of 0.1 to 3 μm.  
     
     
         13 . The method of surface-treating structural components of a nuclear power plant according to  claim 10 , wherein the electroless plating solution is prepared by injecting component substances of the electroless plating solution into the reactor water cleaned by decomposing the chemical decomposition liquid.  
     
     
         14 . The method of surface-treating structural components of a nuclear power plant according to  claim 10 , wherein the structural components of the nuclear power plant are a reactor vessel and reactor internal components, and the electroless plating solution is injected into the reactor vessel.  
     
     
         15 . The method of surface-treating structural components of a nuclear power plant according to  claim 14 , wherein the electroless plating solution is injected into the reactor vessel through at least one of a recirculation system, a reactor cleaning system and a residual heat removing system.  
     
     
         16 . The method of surface-treating structural components of a nuclear power plant according to  claim 10 , wherein after forming a metal film on the surfaces of the structural components of the nuclear power plant by wetting the surfaces of the structural components with the electroless plating solution, exposing the metal film to water of 100° C. or above.  
     
     
         17 . A method of surface-treating structural components of a nuclear power plant, said method comprising disposing an electroless plating solution supply system having an injection nozzle for injecting an electroless plating solution containing at least either an electrical insulating substance or an oxide having a lattice oxygen anion diffusing property between a reactor vessel and a reactor vessel flange, and injecting the electroless plating solution into the reactor vessel by the electroless plating solution supply system.  
     
     
         18 . A nuclear power plant including a reactor vessel and a reactor internal components disposed in the reactor vessel; wherein at least either surfaces of the reactor vessel exposed to reactor water or surfaces of the reactor internal components are coated with a metal film of a metal containing at least either an electrical insulating substance or an oxide having a lattice oxygen anion diffusing property.  
     
     
         19 . The nuclear power plant according to  claim 18 , wherein the electrical insulating substance or the oxide is particles selected from zirconia, alumina, titania, silica, ceria or thoria.