Process for upgrading residua

Abstract

A process for upgrading a residua feedstock using a short vapor contact time thermal process unit comprised of a horizontal moving bed of fluidized hot particles. The residua feedstock is preferably atomized so that the Sauter mean diameter of the residua feedstock entering the reactor is less than about 2500 μm. One or more horizontally disposed screws is preferably used to fluidize a bed of hot particles.

1 . A process for upgrading a residua feedstock to produce an increase in total liquid products in a process unit comprising (i) a heating zone wherein solids containing carbonaceous deposits are received from a stripping zone and heated in the presence of an oxidizing gas; (ii) a short vapor contact time reaction zone containing a horizontal moving bed of fluidized hot solids recycled from the heating zone, which reaction zone is operated at a temperature from about 450° C. to about 700° C. and operated under conditions such that substantially all of the solids that are passed from the heating zone pass through the reaction zone and wherein the solids residence time is from about 5 to about 60 seconds, and the vapor residence time is less than about 2 seconds; and (iii) a stripping zone through which solids having carbonaceous deposits thereon are passed from the reaction zone and wherein lower boiling hydrocarbons and volatiles are recovered with a stripping gas; said process comprising the steps of: 
 (a) atomizing the residua feedstock so that the residua feedstock has a liquid droplet size less than about 2500 μm Sauter mean diameter;  
 (b) passing the atomized liquid residua feedstock to the short vapor contact time reaction zone where it contacts the fluidized hot solids, thereby resulting in high Conradson Carbon components and metal-containing components being deposited onto said hot solids, and a vaporized fraction;  
 (c) separating the vaporized fraction from the solids; and  
 (d) passing the solids to said stripping zone where they are contacted with a stripping gas, thereby removing volatile components therefrom;  
 (e) passing the stripped solids to a heating zone where they are heated to an effective temperature that will maintain the operating temperature of the reaction zone; and  
 (f) recycling hot solids from the heating zone to the reaction zone such that substantially all of the solids that are passed from the heating zone pass through the reaction zone and where they are contacted with fresh feedstock.  
 
     
     
         2 . The process according to  claim 1  wherein the residua feedstock has a liquid droplet size between about 50 μm and about 1000 μm Sauter mean diameter.  
     
     
         3 . The process according to  claim 1  wherein the residua feedstock has a liquid droplet size between about 50 μm and about 700 μm Sauter mean diameter.  
     
     
         4 . The process according to  claim 1  wherein the vapor residence time of the short vapor contact time reaction zone is less than about 1 second.  
     
     
         5 . The process according to  claim 1  wherein the residua feedstock is selected from the group consisting of vacuum resids, atmospheric resids, heavy and reduced petroleum crude oil, pitch, asphalt, bitumen, tar sand oil, shale oil, and coal liquefaction bottoms.  
     
     
         6 . The process according to  claim 5  wherein the residua feedstock is a vacuum resid.  
     
     
         7 . The process according to  claim 4  wherein the solids residence time of the short vapor contact time reaction zone is from about 10 to 30 seconds.  
     
     
         8 . The process according to  claim 1  wherein the particles of the short vapor contact time reaction zone are fluidized with the aid of a mechanical means.  
     
     
         9 . The process according to  claim 8  wherein the mechanical means comprises one or more horizontally disposed screws within the reactor.  
     
     
         10 . The process according to  claim 1  wherein the residua feedstock has a liquid droplet size less than about 700 μm Sauter mean diameter.  
     
     
         11 . A process for upgrading a residua feedstock to produce an increase in total liquid products in a process unit comprising (i) a heating zone wherein solids containing carbonaceous deposits are received from a stripping zone and heated in the presence of an oxidizing gas; (ii) a reaction zone containing a horizontal moving bed of fluidized solids recycled from the heating zone, wherein the solids residence time is from about 5 to about 60 seconds, and the vapor residence time is less than about 2 seconds; and (iii) a stripping zone wherein lower boiling hydrocarbons and volatiles are stripped from the solids using a stripping gas; said process comprising: 
 (a) atomizing the residua feedstock so that the residua feedstock has a liquid droplet size less than about 2500 μm Sauter mean diameter;    (b) passing the atomized liquid residua feedstock to the reaction zone where it contacts the fluidized solids, thereby resulting in high Conradson Carbon components and metal-containing components being deposited onto said solids, and a vaporized fraction;    (c) separating the vaporized fraction from the solids; and    (d) passing the solids to the stripping zone where they are contacted with a stripping gas, thereby removing volatile components therefrom;    (e) passing the stripped solids to the heating zone; and,    (f) recycling the solids from the heating zone to the reaction zone.    
     
     
         12 . The process according to  claim 11  wherein the residua feedstock has a liquid droplet size between about 50 μm and about 1000 μm Sauter mean diameter.  
     
     
         13 . The process according to  claim 12  wherein the residua feedstock has a liquid droplet size between about 50 μm and about 700 μm Sauter mean diameter.  
     
     
         14 . The process according to  claim 13  wherein the vapor residence time of the short vapor contact time reaction zone is less than about 1 second.  
     
     
         15 . The process according to  claim 14  wherein the residua feedstock is selected from the group consisting of vacuum resids, atmospheric resids, heavy and reduced petroleum crude oil, pitch, asphalt, bitumen, tar sand oil, shale oil, and coal liquefaction bottoms.  
     
     
         16 . The process according to  claim 14  wherein the residua feedstock is a vacuum resid.  
     
     
         17 . The process according to  claim 14  wherein the solids residence time of the short vapor contact time reaction zone is from about 10 to 30 seconds.  
     
     
         18 . The process according to  claim 17  wherein the solids in reaction zone are fluidized with the aid of a mechanical means.  
     
     
         19 . The process according to  claim 18  wherein the mechanical means comprises one or more horizontally disposed screws within the reactor.  
     
     
         20 . The process according to  claim 11  wherein the residua feedstock has a liquid droplet size less than about 700 μm Sauter mean diameter.