US12606653B2ActiveUtilityA1

Resin composition and preparation method therefor

Priority: Dec 31, 2019Filed: Dec 30, 2020Granted: Apr 21, 2026
Est. expiryDec 31, 2039(~13.4 yrs left)· nominal 20-yr term from priority
C08L 2207/324C08L 2205/03C08F 2810/40C08L 15/02C08F 132/08C08F 112/12B60C 1/0008C08F 112/08
40
PatentIndex Score
0
Cited by
38
References
11
Claims

Abstract

The present disclosure relates to a rubber composition and a method of preparing the same, the rubber composition comprising a viscosity modifier and a modified polymer having a structure in which a molecular weight regulator is coupled to at least one of both ends of an at least partially hydrogenated or non-hydrogenated petroleum resin. The rubber composition according to the present disclosure has improved processability and thus may replace process oil, and may markedly improve gas impermeability.

Claims

exact text as granted — not AI-modified
What is claimed is: 
     
         1 . A resin composition comprising a modified polymer having a structure in which a molecular weight regulator is coupled to at least one of both ends of an at least partially hydrogenated or non-hydrogenated petroleum resin,
 wherein the resin composition further comprises a viscosity controller, and   wherein the viscosity controller is a low-viscosity liquid resin having a viscosity (25° C.) of 20-500 cps, and   wherein the low-viscosity liquid resin is selected from hydrogenated DCPD-C 9  copolymer resins, hydrogenated DCPD resins, and mixtures thereof.   
     
     
         2 . The resin composition of  claim 1 , wherein the petroleum resin comprises a C 9  monomer-derived repeating unit. 
     
     
         3 . The resin composition of  claim 2 , wherein the C 9  monomer-derived repeating unit comprises vinyltoluene, α-methylstyrene, styrene, dicyclopentadiene, indene, and methylindene. 
     
     
         4 . The resin composition of  claim 1 , wherein the molecular weight regulator is selected from ethyl mercaptan, butyl mercaptan, hexyl mercaptan, dodecyl mercaptan, phenyl mercaptan, benzyl mercaptan, mercaptoethanol, thioglycolic acid, mercapto propionic acid, pentaerythritol tetrakis(3-mercapto) propionate, and mixtures of two or more thereof. 
     
     
         5 . The resin composition of  claim 1 , wherein the resin composition has a number average molecular weight of 200 to 500, and a glass transition temperature of −25 to −15° C. 
     
     
         6 . The resin composition of  claim 1 , wherein the resin composition has a viscosity of 2,000-4,000 cps, as measured at 60° C., and aromaticity of 30% to 50%. 
     
     
         7 . The resin composition of  claim 1 , wherein the resin composition comprises 80-98% by weight and 2-20% by weight of the modified polymer and the viscosity controller, respectively. 
     
     
         8 . A rubber composition including a raw material rubber and the resin composition according to  claim 1 , the rubber composition comprising 5-25 parts by weight of the resin composition, on the basis of 100 parts by weight of the raw material rubber. 
     
     
         9 . The rubber composition of  claim 8 , wherein the rubber composition comprises, on the basis of 100 parts by weight of the raw material rubber, 1-8 parts by weight of a homogenizing agent, 20-80 parts by weight of a reinforcing agent, and 0.1-10 parts by weight of a vulcanization adjuvant. 
     
     
         10 . The rubber composition of  claim 8 , wherein the rubber composition comprises, on the basis of 100 parts by weight of the raw material rubber, 0.1-2 parts by weight of sulfur, and 0.5-5 parts by weight of a vulcanization accelerator. 
     
     
         11 . The rubber composition of  claim 8 , wherein the rubber composition, after being prepared as a rubber specimen, has gas permeability of 90 cm 3 /(m 2 .day.atm) or less, as measured by a KS M ISO 2556 method.

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